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What exactly is a battery? |
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A battery is a source of electrical energy
that keeps supplied with power for a host of gadgets and appliances
that make all of lives easier. A battery is a combination
of cells electrically connected in series and can be considered
as an electrochemical energy conservation system, which converts
into electricity when its terminals are connected to an electrical
appliance. |
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Okay, you ask, what is the difference between a cell and a
battery? |
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Well the smallest item that makes up
a battery is a cell. Cells are joined together within the
battery by soldered or welded contacts. These are all then
housed in a ‘jacket’ of some kind, whether a
wrap or plastic that features the manufacturer’s name,
the voltage of the battery, the battery number etc.
Since the invention of the first battery by LeClanche, way
back when (We won’t bore you with dates and stuff)
the technology of the battery has improved to the point
where we are now able to enjoy complete portability in everything
from cordless phones, cell phones, laptops, digital cameras,
two way radios, etc.
So, below, we have compiled a summary of the different types
of batteries available today, the chemistry involved in
their manufacture, special features along with some general
tips on batteries and battery maintenance.
The list is arranged into two main types: primary batteries
and rechargeable batteries (also called secondary batteries). |
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Non rechargeable or primary
batteries |
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Alkaline
Lithium
Silver Oxide
Zinc Chloride (Heavy Duty)
Carbon Zinc (General) |
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Rechargeables or secondary batteries |
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Nickel-Cadmium
Nickel Metal Hydride
Lithium-Ion
Lead Acid |
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Non rechargeable or primary
batteries |
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Alkaline |
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By far these are the most common battery
on the market today. These are the ones you find in corner
stores and drug stores, etc. Although primarily dominated
by the Energizer and Duracell brand names, other brands
such as Panasonic, Maxwell, Ray-o-Vac and Sanyo are gaining
more market share with a wider and wider range of battery
products.
Alkaline batteries were introduced in the mid 1950’s
and were a huge improvement on the traditional general purpose
or heavy duty batteries of the time. Why? Because firstly,
alkaline batteries pack more ‘punch’ - lasting
much longer in applications, such as flashlights and Walkmans,
for instance, than before. Secondly, they are not adversely
affected by wide fluctuations in temperature, functioning
quite well in sub-zero conditions - a feature not associated
with general purpose batteries. |
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Lithium |
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This is a fairly new ‘kid on the
block’. But again, a big improvement over the alkaline
battery, in many ways. Lithium offers lots of power that releases
steadily and is found mostly in digital camera batteries and
camcorder batteries that require steady reliable chemistry
for light meters and motors, etc. It is also found in high
drain watches that have lots of ‘bells and whistles’
incorporated in them, which can often require up to 3 volts
of power. Lithium batteries are also found as back-up for
computers, laptops, calculators, medical equipment and a whole
range of metering devices etc. |
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Silver Oxide |
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Another excellent battery chemistry that
is found in just about all watch cells. This is an amazing
fact when you think about it…one tiny little watch cell
can keep a watch running for between 3 and 5 years - running
24 hours a day, seven days a week. Pretty impressive technology,
right? Silver oxide is also used in cameras for operating
light meters and a few other applications, but its primary
use is in watch batteries. |
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General Purpose/Heavy
Duty |
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These batteries have dropped off radically
in popularity over the years, in favor of alkaline chemistry.
They can still be used for many applications, like flashlights,
small radios, etc. but they tend to die out quickly and, of
course, there is the temperature problem, where they simply
lay down dead when it gets down to the sub-zero end of the
scale. |
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Rechargeables or secondary
batteries |
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Rechargeable battery technology has
improved immensely over the past ten years or so. A rechargeable
battery is one that offers reversible systems with regard
to its electrochemistry and the structure of the electrodes.
A primary battery discharges its power just once and then
it’s dead. Its internal configuration is generally
more simple than rechargeables as it doesn’t have
to accommodate numerous charges and discharges. Just a word
of caution here, never attempt to charge a primary battery
as it is uneconomical and highly dangerous.
Rechargeable batteries offer sound economy, being capable
of being charged up to 1,000 times during their lifetime.
Rechargeable batteries (Ni-Cads) or Nickel Cadmium were
first manufactured some sixty years ago. They are relatively
inexpensive. They are made in part with cadmium, a deadly
toxic chemical and should be recycled accordingly. Rechargeable
batteries are now also made of Nickel Metal Hydride (NiMH)
and Lithium-Ion (Li-Ion) and also Sealed Lead Acid (used
mostly in automobile batteries and emergency lighting applications).
If left for long periods of time, all rechargeable batteries
will self-discharge. |
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NiCd (Nickel
Cadmium) |
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The first and most prevalent type of rechargeable
found on the market. A real ‘workhorse’ battery.
The one concern you have to address with NiCd batteries is
the ‘memory effect,’ which is caused when the
battery is not completely discharged after each drain cycle.
You must drain these types of batteries completely and then
fully charge again to avoid this problem. NiCd batteries are
not environmentally friendly, as the cadmium is a very nasty
chemistry that can end up leaching into the ground from landfills
etc., when dumped. The memory effect can be sometimes reversed
through using a conditioning charger. This will drain the
battery first, before charging to help eliminate memory effect
build up. |
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NiMH (Nickel
Metal Hydride) |
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This fairly recent entry into the rechargeable
field offer up to 40% additional power capacity that the traditional
NiCd’s of equal size. Another big advantage is that
they do not suffer from the same ‘memory effect.’
Also, from the environmental aspect, too, these batteries
are far more acceptable than NiCd’s, as they will breakdown
with little or no harmful effect on the environment. Nickel
Metal Hydride batteries are commonly found in cell phone applications,
laptop computers and camcorders. They have about 20% more
power than Ni-cad batteries and weigh about 20% less. |
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LiON (Lithium
Ion) |
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This one really is the ‘new kid on
the block’ in portable power. This new battery chemistry
offers twice the run time of a NiMH battery. They, are, of
course, more expensive and are still relatively unknown to
most consumers as they are only found in a limited number
of applications. They last about 400 charges and discharges
and have to be charged in a special charger built specially
for these batteries. They will be seen more and more in the
coming years in various applications as an attractive solution
for manufacturers looking for long-lasting, portable power.
The advantage here is the weight, at some 50% less than Nickel
Metal Hydride, with about the same capacity. That is why they
are now so popular in laptop computers, as they put out a
high degree of efficiency, last a long time and are quite
light. These batteries need a special charger, as they will
only charge up to about 50% capacity if placed in a regular
charging unit. They are now widely used in digital cameras
and camcorders. |
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Sealed Lead
Acid |
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Sealed lead acid chemistry is the grand
old workhorse in the stable of rechargeables. The sealed lead
acid battery is your typical car battery, a series of plates
in a solid case covered in sulphuric acid. Very tough chemistry
for these applications (cars, motorcycles, emergency lighting
systems for apartments buildings etc.) They last a long time
under severe conditions (just think about your car battery)
- a very reliable technology that will be with us for many
years to come. Some lead acid batteries now have a gel inside
instead of acid, which makes them a little less volatile.
They are normally 12 volts or 6 volts in varying amperages.
They are also used extensively in emergency lighting systems. |
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General Tips on Batteries |
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Storage |
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Batteries should be kept in a cool,
dry place away from hazards such as metal touching contacts
and excessive heat. Some people store alkaline batteries
in their refrigerator and there are mixed opinions about
the wisdom and benefits of this. One theory is that the
batteries, being cold, will not drain anywhere near as quickly
while not in use. However, the refrigerator does have a
lot of moisture and, of course, those metal racks could
cause problem. And, is it a good idea to have batteries
around food? Well, only if they are wrapped very carefully
in vapor-proof packaging, otherwise the battery will dry
out in the refrigerator environment and die prematurely.
Also, when taken out of the refrigerator, they should be
allowed to warm up prior to use. Similarly, batteries in
the glove compartment of your car can experience extreme
heat in summer, which will dry out the battery quite quickly
rendering them useless just when you need them (Murphy’s
Law). |
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Memory Effect
In Rechargeables |
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Just a further reminder, nickel cadmium
batteries can develop what is called ‘memory effect’
if they are not charged and discharged adequately. For all
you technical buffs out there this is how it works:
Memory effect is caused by the gathering of bubbles of gas
on the cell plates of the battery, when the battery is not
adequately charged or discharged. These gas bubbles cling
to the battery plates and, of course, reduce the actual
area on the plate surface, which reduces their capacity.
Also, chemical crystals build-up, and can cause the same
problem. Therefore if you charge a battery for just three
hours a number of times, when it’s capable of absorbing
a six hour charge, it will eventually develop a ‘memory,’
locking it into that level of capacity providing only 3
hours run time. The way to avoid this condition is to fully
drain the battery right down before fully charging once
again. Be aware that the greatest danger with any type of
rechargeable battery is overcharging. If you feel a battery
getting hot, either whilst being charged or not, it should
be discarded to avoid explosion and fire. |
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Discharge
Rates In Storage |
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Stored batteries will self discharge at
various rates depending on their electronchemical system.
- Generally speaking, alkaline batteries will discharge
at approximately 2% per year, while zinc carbon (heavy
duty) batteries will release about 4% a year.
- Lithium batteries are very stable and can last up to
ten years and beyond in a suitable storage situation,
losing only 1% power per year.
- Rechargeable batteries, however, drain very quickly
in a storage situation - from between 10% to 25% per month.
- Also temperature can effect this discharge rate. Rule
of thumb is - the higher the temperature, the quicker
the discharge drainage rate for the battery.
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Appliances
and Battery Types |
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Cordless phone batteries use either
nickel cadmium or the newer, nickel metal hydride chemistry.
There are dozens of shapes, sizes and voltages on these
batteries from a whole host of manufacturers. Over 100 million
cordless phones have been sold in the last three years.
This is an enormous market for rechargeable nickel cadmium
and nickel metal hydride chemistry.
Cell phones use either nickel metal hydride or the new Lithium
Ion chemistry. For instance, all of the Nokia batteries
including Nokia 2100, Nokia 5100, Nokia 6110, Nokia 232
models are up-grading to Lithium Ion chemistry. Many of
the Motorola and Ericsson cell phones are also using a combination
of nickel metal hydride and lithium ion chemistry in their
line of cell phones.
Laptop computers almost exclusively use Lithium Ion cells
made up into powerful battery packs.
Digital cameras have a whole series of Lithium Ion batteries
for various models. Also used are high-capacity AA size
batteries in nickel metal hydride. Newer models of digital
cameras by Sony, Panasonic, JVC etc., are now requiring
special Lithium Ion batteries that are ‘smart batteries’
- that is they include micro chips that control and send
data on the power left in the battery. These batteries also
include a safety feature that protects the battery from
over-heating in the event of too much ‘stress’
on the battery pack.
The use of batteries is growing rapidly each year. The new
nickel metal hydride batteries, used extensively now in
digital cameras, rose 27% in 2001. Lithium Ion is also being
introduced in dozens of new applications, but primarily
in digital cameras and camcorders. Cell phones, too, are
becoming more sophisticated in their need for better chemistry
in their battery requirements. Nickel Metal Hydride is slowly
being replaced with the newer Lithium Ion battery.
Cordless phone batteries are also getting more powerful
with the introduction of the longer range 2.4 ghz models.
Cordless phones used to use exclusively Nickel Cadmium batteries,
but now all are coming out with Nickel Metal Hydride and
in some cases Lithium Ion batteries. The cordless phone
market has grown by over 100,000,000 units in three years.
The demand for newer and better batteries for these new
long-range models will continue to grow.
The battery industry is here to stay and growing by leaps
and bounds. As the need for smaller, higher powered batteries
emerges in all kinds of applications including cell phones,
cordless phones, digital cameras, medical, etc., battery
manufacturers will be striving to develop more and more
powerful batteries to meet the consumers’ needs. |
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Any statements and data in this file are
for general information purposes. |
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